无轴承旋翼柔性梁载荷特性研究

应用Hamilton原理建立了双路传力的无轴承旋翼运动方程。采用均匀入流模型,基于直升机飞行平衡条件,建立了无轴承旋翼柔性梁载荷的计算模型,并通过算例验证了模型的精度。利用该模型,研究了全机重心位置、机身气动阻力以及平尾安装角对柔性梁载荷特性的影响,给出了各因素对柔性梁载荷的影响趋势,得出了降低柔性梁载荷的方法。数值结果表明:2cm左右重心位置的变化能够引起9%~11%的柔性梁载荷变化量,15%气动阻力的增加会导致约9%的柔性梁载荷的增大;2°平尾安装角的变化引起约10%柔性梁载荷的变化量,3°平尾安装角的变化引起约26%柔性梁载荷的变化。     

Dynamic relaxation process of a 3D super crystal structure in a Cu:KTN crystal

In this Letter,we report the existence and relaxation properties of a critical phenomenon on called a 3D super crystal that emerges at T=TC?3.5℃,that is,in the proximity of the Curie temperature of a Cu:KTN sample.The dynamics processes of a 3D super crystal manifest in its formation containing polarized nanometric regions and/or polarized clusters.However,with strong coupling and interaction of microcomponents,the characteristic relaxation time measured by dynamic light scattering demonstrates a fully new relaxation mechanism with a much longer relaxation time.As the relaxation mechanism of a relaxator is so-far undetermined,this research provides a novel perspective.These results can help structure a fundamental theory of ferroelectric relaxation.     

Theory and model implementation for analyzing line structures subject to dynamic motions of large deformation and elongation using the absolute nodal coordinate formulation (ANCF) approach

This paper presents the theory development and numerical implementation of a new gradient-deficient-based ANCF (Absolute Nodal Coordinate Formulation) model applied to perform the nonlinear dynamic analysis of elastic line structures subject to large stretching and deformation. The derivations of model equations, introduced numerical approaches, and result validations are the focuses of this study. Different from the traditional rod theory for small stretching consideration, the present model implements the line structures’ large elongation concepts into both the control mechanisms of constitutive formulations and equations of motion. The effect of external hydrodynamic forces on structures is also included in the model formulations. Based on the conservation of energy, the line model developed in this study covers the variation in strain and takes a full account of the bending effect with large stretching. A finite-element-based implicit scheme according to a modified Newmark-beta method is employed to solve the assembled system equations with unknown variables of nodal position vectors, their tangential derivatives, and strains. Selected cases with dynamic motions, such as nonlinear oscillation of a compound pendulum, free falling of a horizontal elastic beam in air with two different settings of gravity, free falling of a submerged horizontal tether with and without an attached concentrated mass, and a submerged vertical tether with a prescribed translational motion, are simulated to verify the developed model by comparing the results with analytical solutions and published experimental data and numerical results. It is found the present ANCF model, as noticed with good matched results with analytical solutions, measurements and other published solutions, is demonstrated to be able to provide converged and reasonably accurate predictions on the responses of line structures subject to large dynamic motions.

     

Trifluoromethylation‐Initiated Remote Cross‐Coupling of Carbonyl Compounds to Form Carbon–Heteroatom/Carbon Bonds

By involving the reversal of conventional reactivity expectations without external oxidants, we describe a novel and convenient protocol of remote cross‐coupling of carbonyl compounds with a series of common and simple nucleophiles. This cross‐coupling is triggered by radical trifluoromethylation of alkenes, thereby achieving highly selective remote difunctionalization of alkenes and α‐position of the carbonyl group for facile access to trifluoromethyl α‐halo‐ and α‐cyanocarbonyl compounds. The reaction exhibits a broad substrate scope with excellent functionality tolerance and many different types of nucleophiles; further synthetic applicability of the obtained compounds proved to be suitable, thus showing great potential for synthetic utility.     

Hierarchical model for strain generalized streaming potential induced by the canalicular fluid flow of an osteon

A hierarchical model is developed to predict the streaming potential(SP) in the canaliculi of a loaded osteon. Canaliculi are assumed to run straight across the osteon annular cylinder wall, while disregarding the effect of lacuna. SP is generalized by the canalicular fluid flow. Analytical solutions are obtained for the canalicular fluid velocity, pressure, and SP. Results demonstrate that SP amplitude(SPA) is proportional to the pressure difference, strain amplitude, frequency, and strain rate amplitude. However, the key loading factor governing SP is the strain rate, which is a representative loading parameter under the specific physiological state. Moreover, SPA is independent of canalicular length. This model links external loads to the canalicular fluid pressure, velocity, and SP, which can facilitate further understanding of the mechanotransduction and electromechanotransduction mechanisms of bones.     

Synthesis and Characterization of a Cu14 Hydride Cluster Supported by Neutral Donor Ligands

The copper hydride clusters [Cu₁₄H₁₂(phen)₆(PPh₃)₄][X]₂ (X=Cl or OTf; OTf=trifluoromethanesulfonate, phen=1,10‐phenanthroline) are obtained in good yields by the reaction of [(Ph₃P)CuH]₆ with phen, in the presence of a halide or pseudohalide source. The complex [Cu₁₄H₁₂(phen)₆(PPh₃)₄][Cl]₂ reacts with CO₂ in CH₂Cl₂, in the presence of excess Ph₃P, to form the formate complex [(Ph₃P)₂Cu(κ²‐O₂CH)], along with [(phen)(Ph₃P)CuCl].     

Dielectric-dependent electron transfer behaviour of cobalt hexacyanides in a solid solution of sodium chloride

Here we emphasise the importance of the dielectric environment on the electron transfer behavior in interfacial electrochemical systems. Through doping cobalt hexacyanide (Co(CN)₆^3–) into single microcrystals of sodium chloride (NaCl), for the first time, we obtained the direct electrochemical behavior of Co(CN)₆^3– which is hardly ever obtained in either aqueous or conventional nonaqueous solutions. DFT calculations elucidate that, as the Co(CN)₆^3– anions occupy the lattice units of NaCl₆^5– in the NaCl microcrystal, the redox energy barrier of Co(CN)₆^3–/4– is decreased dramatically due to the low dielectric constant of NaCl. Meanwhile, the low-spin Co(CN)₆^4– anions are stabilized in the lattices of the NaCl microcrystal. The results also show that the NaCl microcrystal is a potential solvent for solid-state electrochemistry at ambient temperature.     

Simultaneous measurement of methyl tert‐butyl ether and tert‐butyl alcohol in human serum by headspace solid‐phase microextraction gas chromatography–mass spectrometry

The abundant production of methyl tert‐butyl ether (MTBE) and its widespread use have led to an increase in the potential for human exposure. This work described a simple, fast, sensitive, reliable and low‐cost method for the simultaneous measurement of MTBE and its metabolite, tert‐butyl alcohol (TBA) in human serum by headspace solid‐phase microextraction gas chromatography–mass spectrometry. Extraction conditions were optimized and 40 °C, 10 min, 250 rpm and 0.3 g NaCl for a 1 mL sample were the optimal conditions. This method showed good analytical performance in terms of sensitivity with limits of detection in serum (1 mL) of 0.03 µg/L for MTBE and 0.05 µg/L for TBA, accuracy (mean recovery values) from 75.8% to 85.8%, precision (relative standard deviations) <10% and sample stability (biodegradation) <10% after 28 days. A verification experiment proved the reproducibility and stability of this method as well. Finally the method was used to detect 212 specimens, and the internal dose levels for MTBE in human serum were presented in China. Copyright © 2015 John Wiley & Sons, Ltd.